Progressive Low-Grade Metamorphism of a Black Shale Formation, Central Swiss Alps, with Special Reference to Pyrophyllite and Margarite Bearing Assemblages   总被引：1，自引：0，他引：1  

FREY  MARTIN 《Journal of Petrology》1978,19(1):95-135

The unmetamorphosed equivalents of the regionally metamorphosedclays and marls that make up the Alpine Liassic black shaleformation consist of illite, irregular mixed-layer illite/montmorillonite,chlorite, kaolinite, quartz, calcite, and dolomite, with accessoryfeldspars and organic material. At higher grade, in the anchizonalslates, pyrophyllite is present and is thought to have formedat the expense of kaolinite; paragonite and a mixed-layer paragonite/muscovitepresumably formed from the mixed-layer illite/montmorillonite.Anchimetamorphic illite is poorer in Fe and Mg than at the diageneticstage, having lost these elements during the formation of chlorite.Detrital feldspar has disappeared. In epimetamorphic phyllites, chloritoid and margarite appearby the reactions pyrophyllite + chlorite = chloritoid + quartz+ H₂O and pyrophyllite + calcite ± paragonite = margarite+ quartz + H₂O + CO₂, respectively. At the epi-mesozone transition,paragonite and chloritoid seem to become incompatible in thepresence of carbonates and yield the following breakdown products:plagioclase, margarite, clinozoisite (and minor zoisite), andbiotite. The maximum distribution of margarite is at the epizone-mesozoneboundary; at higher metamorphic grade margarite is consumedby a continuous reaction producing plagioclase. Most of the observed assemblages in the anchi-and epizone canbe treated in the two subsystems MgO (or FeO)-Na₂O–CaO–Al₂O₃–(KAl₃O₅–SiO₂–H₂O–CO₂).Chemographic analyses show that the variance of assemblagesdecreases with increasing metamorphic grade. Physical conditions are estimated from calibrated mineral reactionsand other petrographic data. The composition of the fluid phasewas low in X_CO2 throughout the metamorphic profile, whereasX_CH4 was very high, particularly in the anchizone where a_H2Owas probably as low as 0.2. P-T conditions along the metamorphicprofile are 1–2 kb/200–300 °C in the anchizone(Glarus Alps), and 5 kb/500–550 °C at the epi-mesozonetransition (Lukmanier area). Calculated geothermal gradientsdecrease from 50 °C/km in the anchimetamorphic Glarus Alpsto 30 °C/km at the epi-mesozone transition of the Lukmanierarea.  相似文献   

Analyse de 47 Echantillons Géochimiques de Référence par Fluorescence-X (Cu, Ga, Ni, Zn) Et par Absorption Atomique (Cu, Ni, Zn)     

M. QUINTIN  A. MARTIN  A. M. de  KERSABIEC 《Geostandards and Geoanalytical Research》1978,2(2):199-209

47 étalons géochimiques internationaux dont les huit nouveaux étalons de l'USGS ont été analysés par fluorescence-X et absorption atomique pour Ni, Cu, Zn et par fluorescence-X pour Ga.
Les auteurs développment ici pour la fluores-cence-X les problèmes concernant le choix des fonds, le calcul du fond véritable sous-jacent au pic mesuré, les impuretés des tubes et de l'appareillage. Une méthode directe sur échantillon pulvérulent, non destructive, sans aucune préparation est utilisée.
Trois systèmes de fluorescence-X utilisant deux appareillages (Philips PW 1540 et Siemens SSRS 1) et deux tubes molybdène et or sont confrontés et les moyennes comparée à celles d'une méthode d'absorption atomique par mise en solution de l'échantillon (IL 353).
Les résultats obtenus sont comparés soit aux valeurs recommandées, soit aux moyennes calculées à partir de la littérature. On discute tant les accords que les divergences.  相似文献   

A Fluid-Dynamical Study of Crystal Settling in Convecting Magmas   总被引：1，自引：3，他引：1  

MARTIN  DANIEL; NOKES  ROGER 《Journal of Petrology》1989,30(6):1471-1500

Thermal convection in magma chambers is believed to be almostalways highly time-dependent, or ‘turbulent’, andpredicted convective velocities are commonly orders of magnitudelarger than settling velocities for typical crystals calculatedfrom Stokes' Law. To understand crystal settling in magma chamberswe have therefore undertaken a theoretical and experimentalstudy of particle settling in a turbulently convecting fluid. The regime of interest is where the ratio, S, of the Stokes'Law settling velocity, v_s, to the root mean square verticalcomponent of convective velocity, W, at mid-depth in the fluidis less than unity. Although v_s < W, settling is still possiblebecause convective velocities are height-dependent and mustdecrease to zero at the boundaries of the fluid. Particles immediatelyadjacent to the bottom boundary settle out with their full Stokes'settling velocities. At the same time, convection is vigorousenough to ensure that the distribution of particles in the fluidis uniform. It follows that the number of particles in suspensiondecays with time according to an exponential law, and the decayconstant is simply the ratio of v_s to h, the depth of the fluid.Experiments confirm this relationship, at least for low particleconcentrations, provided S < 0.5 and there is no re-entrainmentof particles from the floor of the tank. We apply this relationship to crystals in magma chambers andso calculate residence times for typical crystals. We find thatfor basaltic magmas the predicted residence times are smallcompared with the many thousands of years that a chamber takesto solidify if cooling is dominated by conduction through thecountry rock. We therefore conclude that crystal settling maybe an efficient differentiation mechanism. Significant magmaticevolution may, however, take place on time-scales that are competitivewith these residence times. If the settling of crystals is the rate-limiting step duringthe crystallization of a magma chamber it is expected that asteady state will be achieved at which the rate of supply ofcrystals into the convecting magma by crystallization balancesthe rate at which crystals settle out. We show how this ideacan explain both the lack of hydraulic equivalence in cumulaterocks and the commonly observed discrepancy between the relativeproportions of phenocrysts of various phases in fractionatedbasaltic lavas and the calculated relative proportions of thesemineral phases in the fractionating assemblage. Finally, anattempt is made to calculate the steady-state crystal contentof convecting magma chambers. Comparison of the predicted crystalcontents with the observed phenocryst contents of typical basalticlavas suggests that magma chambers may often cool more rapidlythan would be expected for conduction through the country rockalone.  相似文献   

Characteristic features of pockmarks on the North Sea Floor and Scotian Shelf   总被引：6，自引：0，他引：6  

MARTIN HOVLAND  ALAN G. JUDD†  LEWIS H. KING‡ 《Sedimentology》1984,31(4):471-480

This paper presents the results of a comparative study of pockmarks and associated features appearing on both sides of the North Atlantic: on the Scotian Shelf off Nova Scotia and in the northern North Sea. Pockmarks are formed in seabed material consisting of soft silty clay. The seismic, sonar and lithologic characteristics of the sediments on the Scotian Shelf are remarkably similar to those found in the northern North Sea. Sediment clouds suspended in the water column immediately over the seabed have previously been observed on side-scan records associated with gas-charged sediments on corresponding shallow-seismic records. These and similar observations strongly suggest that most pockmarks are caused by gas efflux through the seafloor. However, the detailed mechanism of formation and the origin of the gas in the sediments is still unknown.  相似文献   

Two decades of ocean CO₂ sink and variability     

C. LE QUÉRÉ  O. AUMONT  L. BOPP  P. BOUSQUET  P. CIAIS  R. FRANCEY  M. HEIMANN  C. D. KEELING  R. F. KEELING  H. KHESHGI  P. PEYLIN  S. C. PIPER  I. C. PRENTICE  P. J. RAYNER 《Tellus. Series B, Chemical and physical meteorology》2003,55(2):649-656

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Ozone and C2–C5 hydrocarbon observations in the marine boundary layer between 45°S and 77°S     

V. GROS†  D. MARTIN  N. POISSON  M. KANAKIDOU  B. BONSANG  F. LE GUERN  E. DEMONT 《Tellus. Series B, Chemical and physical meteorology》1998,50(5):430-448

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Composition and source of the clay-sized fraction of Saalian till in The Netherlands     

SYLVI HALDORSEN  PER JØRGENSEN  MARTIN RAPPOL  PETER A. RIEZEBOS 《Boreas: An International Journal of Quaternary Research》1989,18(2):89-97

The clay mineral composition of a number of Saalian till samples from The Netherlands shows a large variation in smectite and illite abundances. The samples were selected according to their source area, as inferred from coarse erratic components. Specimens containing primarily rock fragments indicative of East and East-Central Baltic areas are associated with no or low smectite percentages in their clay fractions. Those with mainly flint and rock fragments indicative of the West Baltic areas have high smectite contents in the clay. In general the smectite-rich material is found in the lower portions of the Saalian till bed, whereas the smectite-poor occurs in the upper portions. The linkage between very fine and coarse till components in the upper smectite-free parts of the till suggests that this entire till has been subjected to englacial transport over distances of at least 1000 km.  相似文献   

Breeding biology of dark-bellied brent geese Branta b. bernicla in Taimyr in 1990 in the absence of arctic foxes and under favourable weather conditions   总被引：1，自引：0，他引：1  

BERNARD SPAANS  MARTIN STOCK  REW ST. JOSEPH  HANS-HEINER BERGMANN  BARWOLT S. EBBINGE 《Polar research》1993,12(2):117-130

In combination with observations in spring staging and wintering grounds in western Europe, a detailed etho-ecological study of nesting dark-bellied brent geese Branta b. bernicla in western Taimyr, Krasnoyarsk, Russia, was made in 1990. Most brent geese arrived on the breeding grounds from 14–19 June and started nesting within a few days. In the study area 264 nests of breeding brent geese were found, mainly on islands but also along small rivers on the mainland. The mean clutch size was 3.0 and 80% of the eggs hatched. Time budget studies showed that incubating females spent on average 138 minutes per 24 hours on feeding. Despite favourable weather conditions and a low density of arctic foxes, only about one-third of the mature birds in the study area bred. In the autumn an intermediate breeding success of 20% juveniles was recorded in the wintering areas. This was probably due to the relatively poor condition in which the brent geese left their spring staging areas.  相似文献   

Downward longwave radiation in general circulation models: a case study at a semi‐arid continental site     

MARTIN WILD  ROBERT CECHET 《地球，A辑:动力气象学与海洋学》2002,54(4):330-337

The present case study evaluates the downward longwave radiation at the surface (DLR) in several high‐resolution (≈1°) general circulation models (GCMs) using surface observations from a semiarid continental site in New South Wales, Australia (Uardry, 34.39°S, 142.30°E). This site is located on a large grassland plain uniform in both its land use and landcover type, and is therefore particularly well suited for a comparison with GCM grid mean values. Monthly averages of newly constructed clear‐sky and all‐sky DLR climatologies and the resulting cloud‐radiative forcing are compared. It is shown that the GCMs exceed the observed DLR under cloud‐free conditions by 10–20 W m⁻² at this semiarid site on an annual basis, with a strong seasonal dependence. The calculated clear‐sky fluxes are overestimated during the warmer summer season, with large absolute values of DLR, while the biases are reduced in the colder and dryer winter season with smaller fluxes. This gives direct support for recent evidence that the DLR model biases depend systematically on the thermal and humidity structure of the cloudless atmosphere. Fluxes from strongly emitting atmospheres tend to be overestimated, but may be underestimated from atmospheres with smaller emission. This points to common problems inherent in the simulation of the emission from the cloudless atmosphere in current longwave radiation codes.
The comparisons of the all‐sky climatologies at Uardry show that the clear‐sky biases are partly masked in the models with an insufficient cloud‐radiative forcing, thereby counterbalancing the excessive DLR of the cloud‐free atmosphere. On the other hand, when the cloudradiative forcing is improved, the biases in the cloud‐free atmosphere become fully apparent in the all‐sky fluxes.  相似文献   

Ice-marginal debris-flow deposits in western Allgau, southern West Germany     

MAT G.G. DE JONG  MARTIN RAPPOL 《Boreas: An International Journal of Quaternary Research》1983,12(1):57-70

Ice-marginal debris-flow deposits (comparable to deposits elsewhere described as flow tills) are described from glacier-proximal sediments in an Alpine foreland area. Debris-flow deposits are characteristically interstratified with subaeric or subaquatie meltwater deposits, and occur in a wide variety of geomorpho-logical settings. The granulomctric composition of debris-flow deposits is more variable than that of subglacial tills. Within-flow variability may occur as a result of the formation of graded bedding, lateral as well as vertical. Clast fabrics show both random and preferred orientations; unequivocal interpretation of these is not possible. Debris-flow deposits are composed of material derived from various sources: sources from subglaeially-derived debris as well as from previously deposited tills and walerlain sediments can be demonstrated.  相似文献